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  • Title: Synthesis of an A-E gambieric acid subunit with use of a C-glycoside centered strategy.
    Author: Roberts SW, Rainier JD.
    Journal: Org Lett; 2007 May 24; 9(11):2227-30. PubMed ID: 17469838.
    Abstract:
    This paper describes our synthesis of the A-E subunit of gambieric acid (GA) in addition to the synthesis of the A-ring and the C-E tricycle. The use of an enol ether-olefin RCM strategy to couple the A and C-E subunits and, in the process, generate the B-ring is noteworthy.
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