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  • Title: Total synthesis of (-)-conocarpan and assignment of the absolute configuration by chemical methods.
    Author: Clive DL, Stoffman EJ.
    Journal: Chem Commun (Camb); 2007 Jun 07; (21):2151-3. PubMed ID: 17520119.
    Abstract:
    (-)-Conocarpan (1) was synthesized by a method based on radical cyclization, and the absolute configuration was established by chemical degradation; the original 2R,3R-assignment to (+)-conocarpan should be reversed, as suggested by a later chiroptical study of model 2,3-dihydrobenzofurans.
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