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  • Title: Application of the intramolecular isomerisation-aldolisation from allylic alcohols and allylic silyl ethers to the synthesis of indanones and indenones.
    Author: Petrignet J, Roisnel T, Grée R.
    Journal: Chemistry; 2007; 13(26):7374-84. PubMed ID: 17579904.
    Abstract:
    A new access to indanones was discovered through a one-step nickel or iron-mediated transposition of 2-hydroxyisobenzofurans. Starting from the corresponding silylenol ethers, a new one-pot tandem isomerisation-Mukaiyama aldol process was also developed. These versatile strategies will be useful for the preparation of various types of indanones and indenones.
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