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  • Title: Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex.
    Author: Morita M, Obora Y, Ishii Y.
    Journal: Chem Commun (Camb); 2007 Jul 19; (27):2850-2. PubMed ID: 17609797.
    Abstract:
    Base-free catalytic alpha-alkylation of active methylene compounds with primary alcohols was successfully achieved using an [IrCl(cod)](2) complex in the presence of PPh(3) to afford the corresponding saturated alpha-alkylated products in good yields.
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