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  • Title: Adsorption of water on three-dimensional pillared-layer metal organic frameworks.
    Author: Kondo A, Daimaru T, Noguchi H, Ohba T, Kaneko K, Kanoh H.
    Journal: J Colloid Interface Sci; 2007 Oct 15; 314(2):422-6. PubMed ID: 17632118.
    Abstract:
    We showed water adsorption isotherms at 303 K on water-resistant three-dimensional (3-D) pillared-layer metal organic frameworks (MOFs) with 1-D semi-rectangular pores, of which size depends on the length of ligand. The shapes of all three adsorption isotherms are type I by IUPAC classification showing strong water-MOFs interaction. The adsorbed amount of water molecules on the hydrophilic site of carboxylic group in 2-D sheets coincided with the crystal water amount. The adsorption on the hydrophilic sites occurs at similar relative pressure even if the used ligand is different.
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