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  • Title: Medium-sized carbocycles by a zirconocene-catalyzed tandem formal ring expansion-magnesation reaction of alkenyl-substituted cyclic enol ethers.
    Author: Barluenga J, Alvarez-Rodrigo L, Rodríguez F, Fañanás FJ.
    Journal: Org Lett; 2007 Aug 02; 9(16):3081-4. PubMed ID: 17637021.
    Abstract:
    A new regio- and stereoselective zirconocene-catalyzed reaction for the synthesis of medium-sized rings is described. The global reaction supposes a formal ring expansion of a cyclic enol ether to give a functionalized carbocycle.
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