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  • Title: Iodinane- and metal-free synthesis of N-cyano sulfilimines: novel and easy access of NH-sulfoximines.
    Author: Mancheño OG, Bistri O, Bolm C.
    Journal: Org Lett; 2007 Sep 13; 9(19):3809-11. PubMed ID: 17696546.
    Abstract:
    The synthesis of N-cyanosulfilimines can readily be achieved by reaction of the corresponding sulfides with cyanogen amine in the presence of a base and NBS or I2 as halogenating agents. Oxidation followed by C-N bond cleavage affords synthetically useful NH-free sulfoximines.
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