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  • Title: Solvation, solute rotation and vibration relaxation, and electron-transfer reactions in room-temperature ionic liquids.
    Author: Shim Y, Jeong D, Manjari S, Choi MY, Kim HJ.
    Journal: Acc Chem Res; 2007 Nov; 40(11):1130-7. PubMed ID: 17705445.
    Abstract:
    A brief account of recent simulation and theoretical model studies of various solution-phase processes in room-temperature ionic liquids is given. These include structure and dynamics of equilibrium and nonequilibrium solvation, solute rotation and vibrational energy relaxation, and free energetics and dynamics of unimolecular electron-transfer reactions. Special attention is paid to both the aspects shared by and the contrasts with polar solvents under normal conditions. A brief comparison with available experiments is also made.
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