These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Coupled hydrogen-bonding interactions between beta-carboline derivatives and acetic acid.
    Author: Reyman D, Hallwass F, Gonçalves SM, Camacho JJ.
    Journal: Magn Reson Chem; 2007 Oct; 45(10):830-4. PubMed ID: 17729214.
    Abstract:
    In this work, we have analysed the tendency of two beta-carboline derivatives, harmane and norharmane, in the formation of hydrogen bonds. We obtained the (1)H and (13)C NMR spectra of different mixtures of these derivatives with acetic acid (AcOH) in CDCl(3). A cyclic 1:3 complex is proposed between harmane and AcOH, while a 1:2 complex is proposed for norharmane. Chemical shifts at temperatures between 233 and 323 K were measured: lowering the temperature produces the same effect as increasing the amount of AcOH in solution. The (13)C data confirm a delocalisation of the pi electron density towards the pyridinic ring that occurs when AcOH is added.
    [Abstract] [Full Text] [Related] [New Search]