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  • Title: Large-scale synthesis of organophilic zirconia nanoparticles and their application in organic-inorganic nanocomposites for efficient volume holography.
    Author: Garnweitner G, Goldenberg LM, Sakhno OV, Antonietti M, Niederberger M, Stumpe J.
    Journal: Small; 2007 Sep; 3(9):1626-32. PubMed ID: 17786900.
    Abstract:
    We present a multigram scale, one-step nonaqueous synthesis route to monodisperse, highly crystalline ZrO(2) nanoparticles. The nanoparticles can be stabilized in nonpolar solvents via a simple functionalization procedure using only minute amounts of organic stabilizers. Their great potential in materials applications is demonstrated by the fabrication of organic-inorganic nanocomposites that can be selectively photopolymerized to inscribe extremely effective and volume holographic gratings with the highest refractive index contrast (n(1) of up to 0.024) achieved so far.
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