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  • Title: Extending Pummerer reaction chemistry. Synthesis studies in the phakellin alkaloid area.
    Author: Feldman KS, Skoumbourdis AP, Fodor MD.
    Journal: J Org Chem; 2007 Oct 12; 72(21):8076-86. PubMed ID: 17850163.
    Abstract:
    The syntheses of (+/-)-dibromophakellstatin and, from this species, (+/-)-dibromophakellin are described. Oxidative cyclization of a phenylthiolated dihydrooroidin derivative triggered by a Pummerer reaction constitutes the key step in this biomimetic approach to this family of marine alkaloids.
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