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  • Title: A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules.
    Author: Chen B, Ma S, Hurtado EJ, Lobkovsky EB, Zhou HC.
    Journal: Inorg Chem; 2007 Oct 15; 46(21):8490-2. PubMed ID: 17854181.
    Abstract:
    A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5).xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 A, the activated 1a exhibits highly selective sorption behavior toward H(2)/N(2), H(2)/CO, and CO(2)/CH(4).
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