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  • Title: Enantioselective synthesis of the tetrahydrofuran lignans (-)- and (+)-magnolone.
    Author: Nakato T, Yamauchi S.
    Journal: J Nat Prod; 2007 Oct; 70(10):1588-92. PubMed ID: 17887723.
    Abstract:
    The optically pure trisubstituted 7'-oxotetrahydrofuran lignans (-)- and (+)-magnolone ( 1) were synthesized by employing stereoselective S N1 intramolecular cyclization as a key reaction. The absolute configuration of naturally occurring (-)-magnolone was determined as (7 S,8 R,8' S).
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