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  • Title: Advances in the metallotropic [1,3]-shift of alkynyl carbenoids.
    Author: Lee D, Kim M.
    Journal: Org Biomol Chem; 2007 Nov 07; 5(21):3418-27. PubMed ID: 17943198.
    Abstract:
    Metal complexes of alkynyl carbenes undergo a [1,3]-bond shift known as a metallotropic shift. Since the discovery of the metallotropic [1,3]-shift of Rh-carbenoid, many more alkynyl carbene complexes with Ti, Cr, Mn, Mo, Ru, W, Re, Pt, and Au have been discovered to show metallotropic shift behavior. This article briefly summarizes the [1,3]-bond shift of alkynyl carbenes and their metal complexes.
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