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  • Title: Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron.
    Author: Hirano K, Yorimitsu H, Oshima K.
    Journal: Org Lett; 2007 Nov 22; 9(24):5031-3. PubMed ID: 17973483.
    Abstract:
    A nickel catalyst system for beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron has been developed. The catalyst system enables the boration of di-, tri-, and tetrasubstituted substrates in good yields.
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