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  • Title: Phthalimides as exceptionally efficient single electron transfer acceptors in reductive coupling reactions promoted by samarium diiodide.
    Author: Vacas T, Alvarez E, Chiara JL.
    Journal: Org Lett; 2007 Dec 20; 9(26):5445-8. PubMed ID: 18020347.
    Abstract:
    Experimental and theoretical evidence shows that phthalimides are highly efficient single electron transfer acceptors in reactions promoted by samarium diiodide, affording ketyl radical anion intermediates, which participate in high-yielding inter- and intramolecular reductive coupling processes with different radicophiles including imides, oxime ethers, nitrones, and Michael acceptors.
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