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  • Title: Biaryl synthesis via palladium-catalyzed aryne multicomponent coupling.
    Author: Henderson JL, Edwards AS, Greaney MF.
    Journal: Org Lett; 2007 Dec 20; 9(26):5589-92. PubMed ID: 18031056.
    Abstract:
    Aryl iodides have been introduced as electrophiles in the three-component Heck coupling of arynes. Following optimization studies to favor three- versus two-component coupling, the reaction proceeds in good yield to afford a variety of functionalized biaryls.
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