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  • Title: Enantioselective synthesis of aryl sulfoxides via palladium-catalyzed arylation of sulfenate anions.
    Author: Maitro G, Vogel S, Sadaoui M, Prestat G, Madec D, Poli G.
    Journal: Org Lett; 2007 Dec 20; 9(26):5493-6. PubMed ID: 18034497.
    Abstract:
    Arylation of various sulfenate anions generated from beta-sulfinyl esters by retro-Michael reaction in the presence of palladium(0) and enantiopure ligands gave the corresponding aryl sulfoxides in enantio-enriched form. The Josiphos-type ligand (R)-(S)-PPF-t-Bu2 turned out to be the best ligand tested, allowing ee's up to 83% in a predictable sense.
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