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  • Title: A formal synthesis of the callipeltoside aglycone.
    Author: Marshall JA, Eidam PM.
    Journal: Org Lett; 2008 Jan 03; 10(1):93-6. PubMed ID: 18052287.
    Abstract:
    A synthesis of the macrocyclic core structure of callipeltoside A and a C9 epimer has been achieved by applications of chiral vinylzinc or Kishi-Nozaki-Hiyama (K-N-H) additions, Roskamp homologations, and acylketene or intramolecular K-N-H macrolactonizations as key bond-forming steps.
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