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  • Title: Synthesis of functionalized furans via gold(I)-catalyzed Claisen-type rearrangement.
    Author: Istrate FM, Gagosz FL.
    Journal: J Org Chem; 2008 Jan 18; 73(2):730-3. PubMed ID: 18076190.
    Abstract:
    Gold(I)-catalyzed cyclization of pentenynyl allyl ethers allows the rapid construction of functionalized furans. The concerted oxy-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers.
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