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Title: Experimental vibrational spectra of gas-phase tantalum cluster cations. Author: Gruene P, Fielicke A, Meijer G. Journal: J Chem Phys; 2007 Dec 21; 127(23):234307. PubMed ID: 18154382. Abstract: We present gas-phase infrared spectra of tantalum cluster cations containing 6-20 atoms. Infrared multiple photon dissociation of their complexes with argon atoms is used to obtain vibrational spectra in the region between 90 and 305 cm(-1). Many spectra have features in common with the vibrational spectra of the lighter homologs, vanadium and niobium, pointing to a common cluster growth mechanism.[Abstract] [Full Text] [Related] [New Search]