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  • Title: A highly conjunctive beta-keto phosphonate: application to the synthesis of pyridine alkaloids xestamines C, E, and H.
    Author: Corbet M, de Greef M, Zard SZ.
    Journal: Org Lett; 2008 Jan 17; 10(2):253-6. PubMed ID: 18161980.
    Abstract:
    The synthesis of a novel beta-keto gamma-xanthyl phosphonate has been achieved. This highly conjunctive reagent has been utilized in a combination of radical and ionic reactions to create new carbon-carbon bonds. Its usefulness was demonstrated by realizing the first total synthesis of naturally occurring pyridine alkaloids xestamines C, E, and H.
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