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  • Title: Debromodispacamides B and D: isolation from the marine sponge Agelas mauritiana and stereoselective synthesis using a biomimetic proline route.
    Author: Vergne C, Appenzeller J, Ratinaud C, Martin MT, Debitus C, Zaparucha A, Al-Mourabit A.
    Journal: Org Lett; 2008 Feb 07; 10(3):493-6. PubMed ID: 18171071.
    Abstract:
    New debromopyrrole-2-aminoimidazolones, debromodispacamide B (1) and debromodispacamide D (2) were isolated from the sponge Agelas mauritiana, collected in the Solomon Islands. A biomimetic one-step reaction from pseudopeptides 5 and 13 in presence of air oxygen and guanidine gave the chiral form of the natural product stereoselectively.
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