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  • Title: The structural determination of endohedral metallofullerene Gd@C(82) by XANES.
    Author: Liu L, Gao B, Chu W, Chen D, Hu T, Wang C, Dunsch L, Marcelli A, Luo Y, Wu Z.
    Journal: Chem Commun (Camb); 2008 Jan 28; (4):474-6. PubMed ID: 18188472.
    Abstract:
    Although the Gd ion in Gd@C(82) has been shown to lie above the C-C bond on the C(2) axis as an anomalous structure from the MEM/Rietveld analysis, the present XANES study reveals that it lies above the hexagon on the C(2) axis as a normal structure, and Gd oscillates around its equilibrium position with an amplitude increasing with temperature increase.
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