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  • Title: catena-Poly[[[aqua[3-(2-pyridylsulfanyl)propionato N-oxide-kappaO1]copper(II)]-mu-[3-(2-pyridylsulfanyl)propionato N-oxide-kappa3O3:O1,O1'] dihydrate].
    Author: Indrani M, Ramasubramanian R, Kumaresan S, Hu ML, Soriano-García M.
    Journal: Acta Crystallogr C; 2008 Jan; 64(Pt 1):m23-5. PubMed ID: 18216431.
    Abstract:
    In the title complex, {[Cu(C8H8NO3S)2(H2O)] x 2 H2O}n, the Cu(II) cation has a distorted square-pyramidal coordination environment consisting of five O atoms, one from a water molecule, one from an N-O group and the other three from the carboxylate groups of two 3-(2-pyridylsulfanyl)propionate N-oxide anions. The aqua[3-(2-pyridylsulfanyl)propionato N-oxide]copper(II) moieties are bridged by 3-(2-pyridylsulfanyl)propionate N-oxide anions to form an infinite three-dimensional coordination polymer with a zigzag chain structure. The crystal structure is stabilized by hydrogen bonds.
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