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  • Title: Spectroscopic, thermal and voltammetric studies of crystalline complex trans-N,N'-bis(salicylidene)-1',2'-cyclohexanediamine with Cu(II).
    Author: Aslantas M, Tümer M, Sahin E.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2008 Nov 01; 71(1):263-8. PubMed ID: 18249581.
    Abstract:
    The dimeric complex, [C20H20CuN2O2]2, has been prepared and characterized by thermal analysis, IR spectroscopy and single-crystal X-ray diffraction techniques. The Cu atom in the binuclear complex exists in a distorted square-pyramidal configuration, defined by three O atoms and two N atoms. The crystal structure is stabilized by intermolecular C-H...O hydrogen bonding interaction. The electrochemical property of the complex was investigated in CH2Cl2 by cyclic voltammetry at 100 mV s(-1) scan rate.
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