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  • Title: Palladium-catalyzed dehydrogenative cis double phosphorylation of alkynes with H-phosphonate leading to (Z)-bisphosphoryl-1-alkenes.
    Author: Han LB, Ono Y, Shimada S.
    Journal: J Am Chem Soc; 2008 Mar 05; 130(9):2752-3. PubMed ID: 18257571.
    Abstract:
    Dehydrogenative cis double phosphorylation of terminal alkynes with H-phosphonate took place efficiently in the presence of a divalent palladium catalyst to afford (Z)-bisphosphoryl-1-alkenes selectively.
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