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  • Title: Symmetrical and unsymmetrical dizinc complexes as models for the active sites of hydrolytic enzymes.
    Author: Jarenmark M, Kappen S, Haukka M, Nordlander E.
    Journal: Dalton Trans; 2008 Feb 28; (8):993-6. PubMed ID: 18274677.
    Abstract:
    Dinuclear carboxylate-bridged zinc complexes of one symmetric and one asymmetric phenolate-based ligand catalyse the transesterification of 2-hydroxypropyl-p-nitrophenyl phosphate (HPNP) at different rates, with an unsymmetrical complex being more active than a symmetric one.
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