These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: [Catalytic ozonation by ceramic honeycomb for the degradation of oxalic acid in aqueous solution].
    Author: Zhao L, Sun ZZ, Ma J.
    Journal: Huan Jing Ke Xue; 2007 Nov; 28(11):2533-8. PubMed ID: 18290478.
    Abstract:
    Comparative experiments for the degradation of oxalic acid in aqueous solution were carried out in the three processes of ozonation alone, ceramic honeycomb-catalyzed ozonation and ceramic honeycomb adsorption. The results show that the degradation rates of oxalic acid in the ceramic honeycomb-catalyzed ozonation, ozonation alone and ceramic honeycomb adsorption systems are 37.6%, 2.2% and 0.4%, and the presence of ceramic honeycomb catalyst significantly improves the degradation rate of oxalic acid compared to the results from non-catalytic ozonation and adsorption. With the addition of tert-butanol, the degradation rates of oxalic acid in catalytic ozonation system decrease by 24.1%, 29.0% and 30.1%, respectively, at the concentration of 5, 10 and 15 mg x L(-1). This phenomenon indicates that ceramic honeycomb-catalyzed ozonation for the degradation of oxalic acid in aqueous solution follows the mechanism of *OH oxidation, namely the heterogeneous surface of catalyst enhances the initiation of *OH. The results of TOC analysis demonstrate that the process of ceramic honeycomb-catalyzed ozonation can achieve the complete mineralization level without the formation of intermediary degradation products. The experimental results suggest that the reaction temperature has positive relationship with the degradation rate of oxalic acid. The degradation rates of oxalic acid in the ceramic honeycomb-catalyzed ozonation system are 16.4%, 37.6%, 61.3% and 68.2%, at the respective reaction temperature of 10, 20, 30 and 40 degrees C.
    [Abstract] [Full Text] [Related] [New Search]