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  • Title: Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BP(tBu)2]Cu(eta1-N2CR2), [Ph2BP(tBu)2]Cu(CPh2), and [Ph2BP(tBu)2]Cu-N(CPh2)(NCPh2).
    Author: Mankad NP, Peters JC.
    Journal: Chem Commun (Camb); 2008 Mar 07; (9):1061-3. PubMed ID: 18292890.
    Abstract:
    [Ph2BP(tBu)2]Cu-L complexes react with diazoalkanes to generate structurally unusual eta1-diazoalkane adducts, a terminal carbene, and an eta1-azine adduct.
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