These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins.
    Author: Schomaker JM, Boyd WC, Stewart IC, Toste FD, Bergman RG.
    Journal: J Am Chem Soc; 2008 Mar 26; 130(12):3777-9. PubMed ID: 18318538.
    Abstract:
    The use of cobalt dinitrosoalkane complexes in the C-H functionalization of alkenes has been demonstrated. Reaction of a series of alkenes with Me4CpCo(CO)2 in the presence of NO generates intermediate cobalt dinitrosoalkane complexes that can be deprotonated alpha to the nitrosyl group and added to various Michael acceptors. The resultant products can then undergo retrocycloaddition reactions in the presence of the original alkene to regenerate the starting cobalt dinitrosoalkane complex and release the functionalized alkene.
    [Abstract] [Full Text] [Related] [New Search]