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  • Title: Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes.
    Author: Ohmura T, Oshima K, Suginome M.
    Journal: Chem Commun (Camb); 2008 Mar 28; (12):1416-8. PubMed ID: 18338041.
    Abstract:
    Palladium-catalysed cis- and trans-silaboration of terminal alkynes has been developed via the addition of (chlorodimethylsilyl)pinacolborane, followed by a one-pot conversion of the chloro group on the silicon atom to an isopropoxy group.
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