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  • Title: Robust, efficient, and orthogonal synthesis of dendrimers via thiol-ene "click" chemistry.
    Author: Killops KL, Campos LM, Hawker CJ.
    Journal: J Am Chem Soc; 2008 Apr 16; 130(15):5062-4. PubMed ID: 18355008.
    Abstract:
    Dendrimers up to the fourth generation were successfully prepared via the divergent growth strategy using a combination of thiol-ene "click" chemistry and traditional esterification reactions. The thiol-ene reactions were conducted under solvent-free, ambient conditions at room temperature by irradiating with UV light. The fourth-generation dendrimers were subsequently functionalized with carboxylic acid, pyrene, and Fmoc-protected cysteine moieties via thiol-ene reactions.
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