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  • Title: Synthetic studies on maitotoxin. 1. Stereoselective synthesis of the C'D'E'F'-ring system having a side chain.
    Author: Morita M, Ishiyama S, Koshino H, Nakata T.
    Journal: Org Lett; 2008 May 01; 10(9):1675-8. PubMed ID: 18393510.
    Abstract:
    The stereoselective synthesis of the maitotoxin C'D'E'F'-ring system having a side chain has been accomplished through a convergent strategy. The key reactions include Horner-Wadsworth-Emmons coupling of the C'D'E'-ring and the side chain and subsequent construction of the F'-ring by silane reduction of dihydropyran.
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