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  • Title: Ligand-field treatment for the optical and electron paramagnetic resonance spectra of ZnO:V(3+).
    Author: Lin-Hua X.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2008 Dec 01; 71(3):993-5. PubMed ID: 18403255.
    Abstract:
    In this work, a full ligand-field energy matrix (45 x 45) diagonalization treatment for 3d(2) ions in trigonal symmetry C(3v) is performed on the basis of a central metal ion-ligand covalency model including the ligand spin-orbit (SO) coupling. Optical fine structure and electron paramagnetic resonance (EPR) spectra of ZnO:V(3+) are uniformly explained.
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