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  • Title: Ambipolar, high performance, acene-based organic thin film transistors.
    Author: Tang ML, Reichardt AD, Miyaki N, Stoltenberg RM, Bao Z.
    Journal: J Am Chem Soc; 2008 May 14; 130(19):6064-5. PubMed ID: 18412338.
    Abstract:
    We present a high performance, ambipolar organic field-effect transistor composed of a single material. Ambipolar molecules are rare, and they can enable low-power complementary-like circuits. This low band gap, asymmetric linear acene contains electron-withdrawing fluorine atoms, which lower the molecular orbital energies, allowing the injection of electrons. While hole and electron mobilities of up to 0.071 and 0.37 cm2/V.s, respectively, are reported on devices measured in nitrogen, hole mobilities of up to 0.12 cm2/V.s were found in ambient, with electron transport quenched. These devices were fabricated on octadecyltrimethoxysilane-treated surfaces at a substrate temperature of 60 degrees C.
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