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  • Title: Room-temperature Kumada cross-coupling of unactivated aryl chlorides catalyzed by N-heterocylic carbene-based nickel(II) complexes.
    Author: Xi Z, Liu B, Chen W.
    Journal: J Org Chem; 2008 May 16; 73(10):3954-7. PubMed ID: 18412386.
    Abstract:
    The Kumada cross-coupling reaction of a variety of unactivated aryl chlorides, vinyl chlorides, and heteroaryl chlorides catalyzed by nickel(II) complexes containing pyridine-functionalized NHC ligands is described. The catalysts are so active that the reactions proceed at room temperature in excellent yields.
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