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  • Title: Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands.
    Author: Malkov AV, Friscourt F, Bell M, Swarbrick ME, Kocovský P.
    Journal: J Org Chem; 2008 Jun 06; 73(11):3996-4003. PubMed ID: 18447387.
    Abstract:
    Asymmetric Baeyer-Villiger reaction of symmetrical cyclobutanones 1a-j with urea-hydrogen peroxide (UHP) can be catalyzed by a complex of Pd(II) and the new terpene-derived P, N-ligand 7. The resulting lactones 2a-j were obtained in high yields and with good enantioselectivity (< or =81% ee).
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