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  • Title: Indium(i) iodide-catalyzed regio- and diastereoselective formal alpha-addition of an alpha-methylallylboronate to N-acylhydrazones.
    Author: Kobayashi S, Konishi H, Schneider U.
    Journal: Chem Commun (Camb); 2008 May 28; (20):2313-5. PubMed ID: 18473054.
    Abstract:
    Indium(i) iodide was found to catalyze the formal alpha-addition of an alpha-methylallylboronate to various N-acylhydrazones, in the presence of an alcohol additive, to afford the corresponding anti-alpha-adducts with high regio- and diastereoselectivity in high yields.
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