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  • Title: Palladium-pincer complex catalyzed C-C coupling of allyl nitriles with tosyl imines via regioselective allylic C-H bond functionalization.
    Author: Aydin J, Szabó KJ.
    Journal: Org Lett; 2008 Jul 03; 10(13):2881-4. PubMed ID: 18529065.
    Abstract:
    A mechanistically new palladium-pincer complex catalyzed allylation of sulfonimines is presented. This reaction involves C-H bond functionalization of allyl nitriles under mild conditions. The reaction proceeds with a high regioselectivity, without allyl rearrangement of the product. Modeling studies indicate that the carbon-carbon bond formation process proceeds via (eta (1)-allyl)palladium pincer complex intermediates.
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