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  • Title: Efficient and versatile synthesis of new porphyrins bearing an N3O moiety: ligands for mimicking cytochrome c oxidase.
    Author: Ruzié C, Even-Hernandez P, Boitrel B.
    Journal: Org Lett; 2008 Jul 03; 10(13):2673-6. PubMed ID: 18533673.
    Abstract:
    Two new generations of ligands for cytochrome c oxidase mimicking have been designed and synthesized via an efficient, convergent, and versatile synthesis. These porphyrins are functionalized with both an internal nitrogen base on one side and a triaza (N3) or a triaza-phenol (N3O) moiety on the other side, attached to the macrocycle by various spacers. Unlike tailed porphyrins, the triaza motif as well as the nitrogen base are linked by two points.
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