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  • Title: Electrochemical analysis of trifluralin using a nanostructuring electrode with multi-walled carbon nanotubes.
    Author: Wen X, Fei J, Chen X, Yi L, Ge F, Huang M.
    Journal: Environ Pollut; 2008 Dec; 156(3):1015-20. PubMed ID: 18539374.
    Abstract:
    The electroanalytical behaviors of the endocrine-disrupting chemical trifluralin have been studied at a nanostructuring electrode. The nanostructuring electrode was fabricated by coating a uniform multi-wall carbon nanotubes/dihexadecyl hydrogen phosphate (MWNTs/DHP) film on glassy carbon electrode (GCE). The reduction peak currents of trifluralin increased remarkably and the reduction peak potential shifted positively at the nanostructuring electrode, compared with that at a bare GCE. The results showed that this nanostructuring electrode exhibited excellent enhancement effects on the electrochemical reduction of trifluralin. Consequently, a simple and sensitive electroanalytical method was developed for the determination of trifluralin. Under optimal conditions, a linear response of trifluralin was obtained in the range from 5.0 x 10(-9) to 6.0 x 10(-6) mol L(-1) (r=0.998) and with a limit of detect (LOD) of 2.0 x 10(-9) mol L(-1). The proposed procedure was successfully applied to determine trifluralin in soil samples with satisfactory results.
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