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  • Title: Metabolism of (-)-grandisin from Piper solmsianum in Coleoptera and Lepidoptera species.
    Author: Ramos CS, Vanin SA, Kato MJ.
    Journal: Phytochemistry; 2008 Aug; 69(11):2157-61. PubMed ID: 18565552.
    Abstract:
    The biotransformation of the major Piper solmsianum leaf phenylpropanoids, such as the tetrahydrofuran lignan grandisin and derivatives was investigated in the beetle Naupactus bipes as well as in the caterpillars Heraclides hectorides and Quadrus u-lucida. Analysis of fecal material indicated that metabolism occurred mainly through mono- and di-O-demethylation at para positions of 3,4,5-trimethoxyphenyl rings of tetrahydrofuran lignans during digestion by these insects. Additionally, 3-hydroxy-4,5-dimethoxycinnamyl and 3,4,5-trimethoxycinnamyl alcohols were identified in fecal extracts of N. bipes.
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