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  • Title: Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(micro-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene).
    Author: Diebolt O, Braunstein P, Nolan SP, Cazin CS.
    Journal: Chem Commun (Camb); 2008 Jul 21; (27):3190-2. PubMed ID: 18594738.
    Abstract:
    A straightforwardly synthesised complex, [Pd(micro-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.
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