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  • Title: Ruthenium-catalyzed hydroarylations of methylenecyclopropanes: mild C-H bond functionalizations with conservation of cyclopropane rings.
    Author: Kozhushkov SI, Yufit DS, Ackermann L.
    Journal: Org Lett; 2008 Aug 21; 10(16):3409-12. PubMed ID: 18630917.
    Abstract:
    Ring conservation was observed in the first catalytic intermolecular hydroarylation of methylenecyclopropanes via C-H bond functionalization, a remarkable reactivity mode for a transformation proceeding through (cyclopropylcarbinyl)metal intermediates.
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