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  • Title: A new type of self-supported, polymeric Ru-carbene complex for homogeneous catalysis and heterogeneous recovery: synthesis and catalytic activities for ring-closing metathesis.
    Author: Chen SW, Kim JH, Shin H, Lee SG.
    Journal: Org Biomol Chem; 2008 Aug 07; 6(15):2676-8. PubMed ID: 18633523.
    Abstract:
    A novel 2nd generation Grubbs-type catalyst tethering an isopropoxystyrene has been synthesized and automatically polymerized in solution to form a self-supported polymeric Ru-carbene complex, which catalyzed ring-closing metathesis homogeneously, but was recovered heterogeneously.
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