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  • Title: Synthesis of azoxabicyclo[3.3.1]nonanones based on diastereoselective reactions of 1,1-bis(trimethylsilyloxy)ketene acetals with isoquinolines and quinolines.
    Author: Schmidt A, Michalik D, Rotzoll S, Ullah E, Fischer C, Reinke H, Görls H, Langer P.
    Journal: Org Biomol Chem; 2008 Aug 07; 6(15):2804-14. PubMed ID: 18633539.
    Abstract:
    Densely functionalized azoxabicyclo[3.3.1]nonanones were prepared by regio- and diastereoselective condensation of 1,1-bis(silyloxy)ketene acetals with isoquinolinium and quinolinium salts and subsequent regioselective and stereospecific iodolactonization.
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