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  • Title: Asymmetric addition of dimethylzinc to alpha-ketoesters catalyzed by (-)-MITH.
    Author: Wu HL, Wu PY, Shen YY, Uang BJ.
    Journal: J Org Chem; 2008 Aug 15; 73(16):6445-7. PubMed ID: 18646857.
    Abstract:
    This investigation describes the catalytic asymmetric addition of dimethylzinc to alpha-ketoesters in the presence of (-)-MITH ( 5) and triethyl borate as an additive to give the corresponding chiral alpha-hydroxy esters with good yields and high enantioselectivities.
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