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  • Title: First acid dissociation at an aqueous H2SO4 interface with sum frequency generation spectroscopy.
    Author: Miyamae T, Morita A, Ouchi Y.
    Journal: Phys Chem Chem Phys; 2008 Apr 21; 10(15):2010-3. PubMed ID: 18688352.
    Abstract:
    The vibrational sum frequency generation (SFG) spectra of the air-liquid interface of H2SO4-H2O solutions over a wide range of concentrations are measured in the SO stretching region (1000-1300 cm(-1)). The analogy of the concentration dependence of Raman and SFG is indicative of a nearly identical behavior of the first acid dissociation at the air-liquid interface as in the bulk.
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