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  • Title: Diazonamide support studies: stereoselective formation of the C10 chiral center in both the CDEFG and AEFG fragments.
    Author: Lin J, Gerstenberger BS, Stessman NY, Konopelski JP.
    Journal: Org Lett; 2008 Sep 18; 10(18):3969-72. PubMed ID: 18702502.
    Abstract:
    The synthesis of both the AEFG macrolactam and the CDEFG bis-indole/tyrosine units found in the marine natural product diazonamide A is presented. Key to the success of the synthesis is the highly stereoselective direct C-arylation of an oxindole by an aryllead(IV) reagent derived from tyrosine.
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